Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

Activating the inactive: A copper-catalyzed allylic trifluoromethylation of unactivated terminal olefins proceeds under mild conditions to produce linear allylic trifluoromethylated products with high E/Z selectivity (see scheme). The reaction can be applied to a range of substrates bearing numerous...

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Bibliographic Details
Main Authors: Parsons, Andrew T., Buchwald, Stephen Leffler
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: Wiley Blackwell 2013
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