Substrate Distortion and the Catalytic Reaction Mechanism of 5-Carboxyvanillate Decarboxylase

5-Carboxyvanillate decarboxylase (LigW) catalyzes the conversion of 5-carboxyvanillate to vanillate in the biochemical pathway for the degradation of lignin. This enzyme was shown to require Mn(2+) for catalytic activity and the kinetic constants for the decarboxylation of 5-carboxyvanillate by the...

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Bibliographic Details
Main Authors: Vladimirova, Anna, Patskovsky, Yury, Fedorov, Alexander A., Bonanno, Jeffrey B., Fedorov, Elena V., Toro, Rafael, Hillerich, Brandan, Seidel, Ronald D., Richards, Nigel G. J., Almo, Steven C., Raushel, Frank M.
Format: Online
Language:en_US
Published: ACS Publications 2017
Online Access:Vladimirova, A., Patskovsky, Y., Fedorov, A. A., Bonanno, J. B., Fedorov, E. V., Toro, R., … Raushel, F. M. (2016). Substrate Distortion and the Catalytic Reaction Mechanism of 5-Carboxyvanillate Decarboxylase. Journal of the American Chemical Society, 138(3), 826–836. http://doi.org/10.1021/jacs.5b08251
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