Substrate Distortion and the Catalytic Reaction Mechanism of 5-Carboxyvanillate Decarboxylase
5-Carboxyvanillate decarboxylase (LigW) catalyzes the conversion of 5-carboxyvanillate to vanillate in the biochemical pathway for the degradation of lignin. This enzyme was shown to require Mn(2+) for catalytic activity and the kinetic constants for the decarboxylation of 5-carboxyvanillate by the...
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Main Authors: | , , , , , , , , , , |
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Format: | Online |
Language: | en_US |
Published: |
ACS Publications
2017
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Online Access: | Vladimirova, A., Patskovsky, Y., Fedorov, A. A., Bonanno, J. B., Fedorov, E. V., Toro, R., … Raushel, F. M. (2016). Substrate Distortion and the Catalytic Reaction Mechanism of 5-Carboxyvanillate Decarboxylase. Journal of the American Chemical Society, 138(3), 826–836. http://doi.org/10.1021/jacs.5b08251 |
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