Selective hydrosilylation of 1,3-diynes catalyzed by titania-supported platinum

Titania-supported platinum (mainly as Pt(II)) has been found to effectively catalyze the hydrosilylation of 1,3-diynes at 70 °C with low catalyst loading (0.25 mol %) under solvent-free conditions. Monohydrosilylation was achieved for diaryl-substituted diynes, whereas dialkyl-substituted diynes wer...

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Bibliographic Details
Main Authors: Alonso Valdés, Francisco, Buitrago Sierra, Robison, Moglie, Yanina, Sepúlveda-Escribano, Antonio, Yus Astiz, Miguel
Other Authors: Universidad de Alicante. Departamento de Química Orgánica
Format: info:eu-repo/semantics/article
Language:eng
Published: American Chemical Society 2012
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Online Access:http://hdl.handle.net/10045/22202

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